Resolving The Pure Enantiomers Of Phenylethylamine Environmental Sciences Essay

The goal of this examination lab was to choose the unadulterated enantiomorphs of (  ± ) - ?- phenylethylamine ( racemic ) blend, by partitioning their diasteriomeric determined capacities using ( + ) - tartaric corrosive. The contrasting enantiomorphs structure various salts with acids. Two atoms that are enantiomorphs have about vague physical and substance belongingss despite the fact that this might be valid, the salts that are shaped after the response with corrosive have recognizable belongingss. A few salts are less solvent [ ( + ) ( †) ] than others, and thus take shape from the blend in an about unadulterated stereoisomeric signifier. While using NaOH as a solid base to deal with the salt, it takes into consideration the separation of the enantiomorph ( Lab Manual, 2007 ) . Polarimetry is a typical technique used to isolate between enantiomorphs, in view of their capacity to spin the plane of enraptured noticeable radiation in inverse waies ( + and †) . This perm its the perceiver to discover the enantiomeric virtue, and consequently the making out of the blend ( Wade, 2007 Synthetic Chemical response: ( †) - amine ( + ) - amine less solvent salt [ ( †) ( + ) ] : solidifies increasingly dissolvable salt [ ( + ) ( + ) ] stays in arrangement 2NaOH+ 2H2O( †) - ?- phenylethylamine ( Lab Manual, 2007 ) Methodology: On the other hand of using a 50 milliliter container to heat up the amine arrangement in, we utilized a 50 milliliter Erlenmyer jar For the rest of the proceduce allude to pg. 18, 22-24 ( Lab Manual, 2007 ) Perceptions: The precious stones were given a 4 hebdomad crystallization period and a short time later, the ( †) - ?- phenylethylamine-( + ) - hydrogen tartrate salt was seen to be a white crystalline strong, and the methyl liquor was a crystalline fluid. Two extremely recognizable beds were seeable after the response with the NaOH ( solid base ) and extra of the methylene chloride ( CH2Cl2 ) . The top bed was translucent in some topographic focuses and misty in others, extremely shady, white fluid, while the base bed was crystalline what's more fluid. The specialist blend following the three separate extractions was near straightforward Outcomes: Table 1: Experimental Datas: Multitudes and Optical Rotations Mass Channel Paper 0.58 g Channel Paper + Initial Crystal Sample 8.25 g Recouped Crystal Sample 7.67 g 50 milliliters Erlenmeyer Flask with 2 bubbling rocks 39.75 g 50 milliliters Erlenmeyer Flask with Amine product and 2 bubbling rocks 42.63 g Amine stock 2.88 g Optical Rotation Explicit Rotation of ( †) - ?- phenylethylamine - 31.8o Table 2: Experimental Raw Given Data Volume of (  ± ) - ?- phenylethylamine 10.0 milliliter Thickness of (  ± ) - ?- phenylethylamine 0.9395 g/mL Sub-atomic Weight of ( †) - ?- phenylethylamine 121.8 g/mol Sub-atomic Weight of ( + ) - tartaric corrosive 150.09 g/mol [ ? ] D ( †) - ?- phenylethylamine - 40.4o  ± 0.2o Table 3: Multitudes, Moles, Optical Purity, and % Output Mass (  ± ) - ?- phenylethylamine 9.40 g Gram particles (  ± ) - ?- phenylethylamine 0.0776 mol Gram particles ( †) - ?- phenylethylamine 0.0388 mol Gram particles of tartaric corrosive: 0.0388 mol Rate Output of ( †) - ?- phenylethylamine-( + ) - hydrogen tartrate 73.1 % Rate Output of ( †) - ?- phenylethylamine 61.3 % Optical Purity 83.7 % Counts: % Output of ( †) - ?- phenylethylamine-( + ) - hydrogen tartrate: Mass (  ± ) - ?- phenylethylamine Gram atoms (  ± ) - ?- phenylethylamine m (  ± ) - ?- phenylethylamine = thickness ten volume = 0.9395 g/mL X 10 milliliter = 9.40 g N (  ± ) - ?- phenylethylamine = mass/atomic weight = 9.40 g/121.18 g/mol = 0.0776 mol Gram atoms ( †) - ?- phenylethylamine and tartaric corrosive: N ( †) - ?- phenylethylamine = 0.0776 mol/2 = 0.0388 mol *Racemic blend so separated by 2* ( half of whole moles ) N ( + ) - tartaric acerb = N ( †) - ?- phenylethylamine = 0.0388 mol Hypothetical Output of ( †) - ?- phenylethylamine-( + ) - hydrogen tartrate: Real Output of ( †) - ?- phenylethylamine-( + ) - hydrogen tartrate: m ( †) - ?- phenylethylamine-( + ) - hydrogen tartrate = n x M = 0.0388 mol X ( 121.18 g/mol + 150.09 g/mol ) = 10.5 g m ( †) - ?- phenylethylamine-( + ) - hydrogen tartrate = Mass channel paper + starting precious stone example †Mass channel paper = 8.25 g †0.58 g = 7.67 g Rate Output of ( †) - ?- phenylethylamine-( + ) - hydrogen tartrate: % Output = ( Actual Yield/Theoretical Yield ) X 100 % I? Real ( what was acquired after analysis ) = ( 7.67 g/10.5 g ) X 100 % I? Hypothetical ( the mass that should hold been = 73.1 % got if all aminoalkane was extricated ) % Output of ( †) - ?- phenylethylamine: Hypothetical Output of ( †) - ?- phenylethylamine Real Output of ( †) - ?- phenylethylamine Since the underlying blend was racemic: m ( †) - ?- phenylethylamine = m (  ± ) - ?- phenylethylamine/2 = 9.40 g/2 = 4.70 g m ( †) - ?- phenylethylamine = mflask w/amine+ rocks - mflask w/rocks = 39.75 g †42. 63 g = 2.88 g Rate Output of ( †) - ?- phenylethylamine % Output = ( Actual Yield/Theoretical Yield ) X 100 % I? Real ( what was gotten after examination ) = ( 2.88 g/4.70 g ) X 100 % I? Hypothetical ( the mass that should hold been = 61.3 % acquired if all aminoalkane was removed Optical Purity of Sample: Hypothetical Optical Purity: Genuine Optical Purity: Optical Purity = - 40.4o  ± 0.2o Explicit Rotation ( [ ? ] D ) : =Optical Rotation [ ? ( watched ) ]/c * 1 = - 31.8o/( 1.0 diabetes mellitus x 0.94 g/mL ) = - 33.8o Optical Purity: = ( Actual optical virtue got/hypothetical optical immaculateness ) X 100 % = - 33.8o/ - 40.4o x 100 % = 83.7 % Conversation: When the ( + ) - tartaric corrosive was added to the racemic blend, (  ± ) - ?- phenylethylamine, ( †) - amine-( + ) - hydrogen tartrate, and ( + ) - amine-( + ) - hydrogen tartrate salts were shaped. The ( †) - amine-( + ) - hydrogen tartrate was considerably less solvent in methyl liquor, and thus solidified out of the arrangement ( Lab Manual, 2007 ) . This strategy for partition was demonstrated to be somewhat fruitful, as the per centum yield of this crystallization was 73.1 % , which is nearly high. The nearness of drosss, each piece great as the powerlessness to entirely take shape the salt from methyl liquor most presumably credited to any differences. It is other than conceivable that despite the fact that the ( †) ( + ) salt is less dissolvable than different salts, it despite everything has a dissolvability, and consequently takes shape rather simple ( subsequently the mandatory 2 hebdomad holding up period, in our example it was 4 hebdomads ) . As great, different salts, notwithstanding their high solvency in methyl liquor, may keep despite everything solidified actually to some degree over the long holding up period, adding to drosss Expansion of NaOH brought about the arrangement of two discernable beds: a white, shady watery bed ( top ) , and a reasonable aminoalkane bed ( underside ) , and took into account the separation of ( †) - ?- phenylethylamine ( Lab Manual, 2007 ) . The extra of 5 milliliter of H2O to the jar affirm that the top bed was the fluid bed, since it expanded relative to the base bed and the H2O was ingested here ( Lab Manual, 2007 ) . The watery bed comprised of the ( †) - amine, alongside Na tartrate, and H2O, while the aminoalkane bed incorporated any drosss. The Na tartrate promptly broke up in H2O, while methylene chloride ( CH2Cl2 ) was added to become dim ( †) - ?- phenylethylamine ( breaking point ~ 186oC ) , since it had a lower breaking point ( 40oC ) , and could simple be evacuated through warming ( Synthesis and statement of alpha-phenyethylamine. After a filtration methodology, including a progression of extractions, there was per centum yield of 61.3 % for the ( †) - ?- phenylethylamine, which is a lower yield than the first 73.1 % , bespeaking that there was lost aminoalkane during the second part of the exploratory procedure. The central reason for this misstep was the incidental removal of a great part of the aminoalkane bed, in which a little whole of ( †) - ?- phenylethylamine was as yet present. The nearness of some drosss may hold other than influenced results, in any case, they would hold then again expanded the yield and lead to misleading outcomes. Another conceivable reason for botch is the little getaway out of the glass plug on the separatory channel when the arrangement was shaken. There was a spot of arrangement that spilled out the underside or spurted out the top when given up ofing the power per unit territory in the channel. Along these lines, the error that all around brought down the yield of t he product extraordinarily builds the optical immaculateness of the blend. The learned turning movement of the finishing up test was - 31. 8o ( levorotatory, left manus revolving movement ) and the particular rotating movement was - 33.8o contrasted and the experimental explicit rotational movement of - 40.4o  ± 0.2o ( Lab Manual, 2007 ) . The specialist optical immaculateness was 83.7 % , which is well high. Beside the prior referenced removal of the natural bed, army different slip-ups, for example, the nearness of drosss may hold added to divergences in the optical virtue. The negative ( adversarial clockwise ) turning movement fundamentally affirmed that the enantiomorph being disengaged was the ( †) - ?- phenylethylamine, and the high optical virtue showed that the extraction was practiced with much achievement and impressive truth, since the closing product was mostly ( †) - amine, in spite of the similarly low yield.

Introducing Improvements to Children Abuse Reporting System

Theoretical The paper is associated with the examination of the nature of the present kid misuse report frameworks in view of the major issues in the circle of childcare. There is an extraordinary issue as far as recognizing the idea of kid misuse, just as data got by childcare experts. Accordingly, the proposition try to set up elective preparing programs both for the clinicians and for parents.Advertising We will compose a custom proposition test on Introducing Improvements to Children Abuse Reporting System explicitly for you for just $16.05 $11/page Learn More Problem Statement Nowadays, the situation in the circle of kid misuse revealing framework is questionable on account of the ascent of abuse among kids. Evidently, the circumstance is foreordained by the carelessness of the legislature to youngster misuse announcing framework, just as the nature of data acquired by the clinicians. Therefore, numerous kids experience the ill effects of consistent maltreatment. Absence of subs idizing in the circle of announcing can give much increasingly monetary issues to the administration in light of the extra asset for youngsters to screen their passionate, mental, and physical state. All the more significantly, absence of instruction among the experts dealing with kids ought to likewise be improved on the grounds that it relies to a great extent upon the detailing administrations. This chain can be contorted and, along these lines, the legislature should look for other proficient methodologies for observing the kids wellbeing. Reason for the Proposal The motivation behind the proposition is to present another activity plan for upgrading clinicians’ mindfulness and improve straightforwardness of youngsters misuse detailing. Specifically, it is firmly recommended that the experts managing youngsters take up program on improving their relational abilities to have the option to meet children’s concerns and needs. Foundation of the Proposal In this regard, there is a difficult issue as far as the collaboration between announcing frameworks and professionals’ recognition. Before introducing the arrangements and a grouping of errands, it is additionally fundamental to characterize the idea of the issue, just as feature different types of kid misuse, including abuse and youngster disregard. In this regard, Levi and Portwood contend that distinctions in definitions regularly keep the doctors from making sensible giving an account of the reality of youngsters misuse (63). In spite of the fact that the degree of doubt isn't legitimized, there ought to be a few boundaries for the clinicians to build up child’s maltreatment.Advertising Looking for proposition on sociologies? How about we check whether we can support you! Get your first paper with 15% OFF Learn More Lack of modern mental research on family childhood frequently contribute contrarily to choosing whether the ebb and flow measures are adequate for sensible youngster misuse announcing in light of the fact that there are cases uncovering no proof for real wounds. The pie outline beneath likewise pictures data on age scopes of kid misuse, which specifies that prior ages as the most powerless against abuse. Survivors of Child Abuse in Relation to Age (Gill 31) Sources of Information The program portrayal gave by Gill will be utilized as a reason for arranging the preparation gatherings for childcare callings. Specifically, Gill contends that social insurance experts ought to be significantly more mindful and touchy in the event that they presume the instance of youngster misuse (36). Past research likewise exhibits issues with youngster security previously. In particular, there is proof that the appropriately masterminded youngster misuse announcing frameworks fundamentally diminished the quantity of childe misuse fatalities (Lindsey 41). So as to characterize different components of family relations, it is important to allude to White et al who ex press their interests associated with the nature of the revealing frameworks, just as the laws supporting the best possible guideline of all detailing systems (White et al. 34). Correspondence investigation is additionally introduced the revealing framework examination. As indicated by Appleton and Nicky Stanley, â€Å"†¦the significance of good multi-office and interdisciplinary working and viable correspondence and data sharing is constantly upheld in strategy records and practice guidance† (153). In this way, this propensity ought to likewise serve the premise of the given project.Advertising We will compose a custom proposition test on Introducing Improvements to Children Abuse Reporting System explicitly for you for just $16.05 $11/page Learn More Proposed Tasks Introducing a program for clinician on learning the standards of conduct and activity plans. Since there is no an exact standard that can recognize the instance of kid misuse, the program ought to be planned for extending information on the professionals dealing with youngster mental and physical wellbeing. In particular, they ought to be proficient of all hazard variables and meanings of kid misuse, including disregard, abuse, sexual and physical maltreatment, badgering, and so forth. Moreover, the program additionally tries to obscure the expert limits to think about youngsters abuse. Empowering instructive projects for child’s parent to forestall the instance of youngster misuse. The significance of announcing ought to likewise concern guardians ought to understand the handiness and need of top notch youngsters misuse detailing frameworks (Bunting et al 187). Building up normal gatherings and meetings to share experience concerning youngsters with extraordinary necessities. Setting up meeting and gatherings will essentially upgrade shared dynamic both between childcare experts and guardians and among guardians and kids. There ought to be an accord between the two gatherings c oncerns since it will permit not exclusively to lessen the recurrence of youngsters abuse, yet in addition to forestall the genuine maltreatment with respect to guardians. Hierarchical Pattern All the above introduced errands can be started all the while on the grounds that they perform different capacities that don't rely upon one another. Specifically, the first is intended for clinicians, the subsequent undertaking tries to improve parents’ demeanor, and last stage is worried about the general open doors for kid social insurance circle. Along these lines, around multi month will be required to work out the procedures of preparing and set up the principles and gauges for attendance.Advertising Searching for proposition on sociologies? We should check whether we can support you! Get your first paper with 15% OFF Find out More Experience The initiators of the program have led top to bottom examination and research of mental, social, and monetary elements impacting the relations in families that could prompt abuse and disregard. Their experience is adequate to meet the necessities of the program. Spending plan The subsidizing should concentrate on staff compensations, just as premises for arranging gatherings, introductions and gatherings. For a month program, $ 10000 will be sufficient to give improvement to children’s treatment and wellbeing. Works Cited Appleton, Jane V., and Nicky Stanley. â€Å"Communicating With Children’s Social Services And Reporting Systems.† Child Abuse Review 19.3 (2010): 153-157. Print. Hitting, Lisa, Anne Lazenbatt, and Isla Wallace. â€Å"Information Sharing And Reporting Systems In The UK And Ireland: Professional Barriers To Reporting Child Maltreatment Concerns.† Child Abuse Review 19.3 (2010): 187-202. Print. Gill, Donna, F. â€Å"Identifying C hild Abuse†. Clinician Reviews, 22.3 (2012): 29-36. Print. Levi, Benjamin, H., and Sharon, G. Portwood. â€Å"Reasonable Suspicion Of Child Abuse: Finding A Common Language.† Journal Of Law, Medicine Ethics 39.1 (2011): 62-69. Print. Lindsey, Duncan. â€Å"Mandated Reporting and Child Abuse Fatalities: Requirements for a System to Protect Children.† Social Work Research 18.1 (1994): 41. Print. White, et al. â€Å"Effect Of Child Protective Services System Factors on Child Maltreatment Rereporting.† Child Welfare 89.3 (2010): 33-55. Print. This proposition on Introducing Improvements to Children Abuse Reporting System was composed and presented by client Lina L. to help you with your own examinations. You are allowed to utilize it for research and reference purposes so as to compose your own paper; be that as it may, you should refer to it as needs be. You can give your paper here.

List Of Current Wikileaks Mirrors Access When Main Site (.ORG) Is Down

List Of Current Wikileaks Mirrors Access When Main Site (.ORG) Is Down Make Money Online Queries? Struggling To Get Traffic To Your Blog? Sign Up On (HBB) Forum Now!List Of Current Wikileaks Mirrors Access When Main Site (.ORG) Is DownUpdated On 20/02/2016Author : Pradeep KumarTopic : TechnologyShort URL : http://hbb.me/1IWNAPj CONNECT WITH HBB ON SOCIAL MEDIA Follow @HellBoundBlogEveryDNS.net which provided DNS services to the Wikileaks.org domain terminated them at 10 PM EST, December 2, 2010, citing threats to the stability of their infrastructure. They believed the DDoS attack on WikiLeaks will become a threat to the service and its other users. Earlier Amazon’s Web Services refused to host Wikileaks for some reason.The management from EveryDNS.net announced this message,EveryDNS.net provided domain name system (DNS) services to the wikileaks.org domain name until 10PM EST, December 2, 2010, when such services were terminated. As with other users of the EveryDNS.net network, this service was provided for free. The termination of services was ef fected pursuant to, and in accordance with, the EveryDNS.net Acceptable Use Policy.More specifically, the services were terminated for violation of the provision which states that Member shall not interfere with another Member’s use and enjoyment of the Service or another entity’s use and enjoyment of similar services. The interference at issues arises from the fact that wikileaks.org has become the target of multiple distributed denial of service (DDOS) attacks. These attacks have, and future attacks would, threaten the stability of the EveryDNS.net infrastructure, which enables access to almost 500,000 other websites.Thus, last night, at approximately 10PM EST, December 1, 2010 a 24 hour termination notification email was sent to the email address associated with the wikileaks.org account. In addition to this email, notices were sent to Wikileaks via Twitter and the chat function available through the wikileaks.org website. Any downtime of the wikileaks.org website has resulte d from its failure to use another hosted DNS service provider..bbpBox10567274838622208{background:url(http://a3.twimg.com/profile_background_images/3147857/WL_Hour_Glass.jpg) #9AE4E8;padding:20px}p.bbpTweet{background:#fff;padding:10px 12px 10px 12px;margin:0;min-height:48px;color:#000;font-size:18px!important;line-height:22px;-moz-border-radius:5px;-webkit-border-radius:5px}p.bbpTweet span.metadata{display:block;width:100%;clear:both;margin-top:8px;padding-top:12px;height:40px;border-top:1px solid #fff;border-top:1px solid #e6e6e6}p.bbpTweet span.metadata span.author{line-height:19px}p.bbpTweet span.metadata span.author img{float:left;margin:0 7px 0 0;width:38px;height:38px}p.bbpTweet a:hover{text-decoration:underline}p.bbpTweet span.timestamp{font-size:12px;display:block}WikiLeaks,org domain killed by US everydns.net after claimed mass attacks KEEP US STRONG https://donations.datacell.com/less than a minute ago via webWikiLeakswikileaksREADHOW TO: Vote For Julian Paul Assange TIM E's 2010 Person Of The Year [ONLINE]You can use the following mirrors which almost points to the main site. You can access the Wikileaks related stuffs using these mirrors. The site is also accessible from the IP address http://213.251.145.96/.Update : Few of the below mentioned mirrors are down I believe, still you can use the IP address and other links.wikileaks.org Official Wikileaks Page [46.51.171.90, 184.72.37.90]cablegate.wikileaks.org Secret US Embassy Cables [91.194.60.90, 91.194.60.112, 204.236.131.131]chat.wikileaks.org Secure SSL Chat Page [88.80.13.160]sunshinepress.org Secure Document Submission Page [88.80.2.32]wikileaks.com Points to Official Site [88.80.13.160]wikileaks.net Points to Official Site [88.80.13.160]wikileaks.biz Points to Official Site [88.80.13.160]wikileaks.de Points to Official Site [88.80.13.160]wikileaks.eu Points to Official Site [88.80.13.160]wikileaks.fi Points to Official Site [88.80.13.160]wikileaks.mobi Points to Official Site [88. 80.13.160]wikileaks.nl Points to Official Site [88.80.13.160]wikileaks.pl Points to Official Site [88.80.13.160]wikileaks.us Points to Official Site [88.80.13.160]ljsf.org Points to Official Site [88.80.13.160]Real mirrors on different IP Addresseswikileaks.info Mirror hosted in Switzerland [62.2.16.94]wikileaks.se Mirror hosted in Sweden [88.80.6.179]nyud.net Mirror hosted in the United States [129.170.214.192]Important Wikileaks Linkstwitter.com/wikileaks Official Wikileaks Twitter Pagefacebook.com/wikileaks Official Wikileaks Facebook PageWikileaks Mirrors Source Wikileaks.info

The Picture Of A Photograph - 923 Words

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A Brief Description of Alex Rodriguez - 692 Words

The star third-baseman, the man with the incredible swing, and the quarter billion dollar man. All these things can be used to describe Alex Rodriguez but now you can add cheater, liar, and drug abuser. Alex Rodriguez, also known as A-Rod, has been involved in an investigation going on for over a year about his use of performance-enhancing steroids. Starting on January 29th, 2013 Alex Rodriguez’s name was included in an article by the Miami New Times that link him to Biogenesis, an anti-aging clinic that had been discovered to be supplying MLB players with performance-enhancing drugs. Rodriguez, along with star right fielder Ryan Braun and 17 others, became part of the longest doping suspension in history. All of the other players accepted the 50-60 game suspensions, but Rodriguez would receive an unprecedented 211 game suspension. This caused Rodriguez to appeal. 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Imporant Decisions In Huck Finn Essay Example For Students

Imporant Decisions In Huck Finn Essay Important decisions made by the protagonist in The Adventures of Huckleberry FinnHuck Finn, the protagonist, made many story altering decisions throughout the novel. Three monumental decisions are lying to the bounty hunters about Jim, tearing up the letter to Miss Watson about Jim and himself, and hiding the gold the duke and the king conned out of the Wilks. Two of the choices by Huck decide the fate and freedom of a human being, Jim, making them very powerful decisions that he has to make. Huck often makes these decisions rashly but they turn out to work very well for him. The three important decisions and why and how he made them show deeply how Huck Finn thinks and feels. One of Hucks major decisions not involving Jim is turning his back on the king and the duke, by hiding the Wilks gold. Huck more or less goes along with the duke and the kings plans until this one because of how nice the Wilks girls are to him. Huck had many choices and could have stuck with the duke and the king but changes his mind after Mary Jane and Susan are so nice to him and scold Joanna for questioning him. After Mary Jane scolds her Huck says to himself this is the girl Im letting that old reptile rob of her money! (169). Mary Jane and Susan make Joanna apologize to Huck and Joanna apologizes so beautiful it was good to hear (169). Joanna apologizing and Mary Jane and Susan sticking up for him makes Huck like them so much that he feels so ornery and low down and mean that I says to myself, my minds made up; Ill hive that money for them or bust(169). Huck then goes to bed early and sneaks up to the king and dukes room to steal the money. When the king and the duke talk about just taking the six thousand they already have and knocking off and lighting out(170). it makes Huck feel pretty bad(170). Huck feeling bad shows that he still believes what he is doing is right and wants to punish the king and the duke and have them get caught and shown for the frauds they are. Over the long term Huck does regret being involved in the downfall of the royalty, he says when he sees the king and the duke tarred and feathered that I felt sorry for them pitiful rascals. . . and felt kind of . . . to blame(222). Another major decision by Huck about Jims freedom is Huck deciding to rip up the letter he was going to write to Miss Watson about where Jim is being held until the reward is paid.. Huck decides to write the letter in chapter thirty-one after he discovers that Jim has been sold by the king and the duke for money. Huck can not think of a plan to get Jim free and has no idea where Jim is so he says to himself Once I said to myself it would be a thousand times better for Jim to be a slave at home where his family was, as long as hed got to be a slave, and so Id better write a letter to Tom Sawyer and tell him to tell Miss Watson where he was (204). Huck then thinks that if Jim is given back to Miss Watson he will be treated badly or sold down the river again for being ungrateful and trying to run away. He also thinks that people will look at him badly for trying to help a slave run away. Huck is then hit by the hand of Providence (204). .u722ec82276fd1bd606d486b304091d59 , .u722ec82276fd1bd606d486b304091d59 .postImageUrl , .u722ec82276fd1bd606d486b304091d59 .centered-text-area { min-height: 80px; position: relative; } .u722ec82276fd1bd606d486b304091d59 , .u722ec82276fd1bd606d486b304091d59:hover , .u722ec82276fd1bd606d486b304091d59:visited , .u722ec82276fd1bd606d486b304091d59:active { border:0!important; } .u722ec82276fd1bd606d486b304091d59 .clearfix:after { content: ""; display: table; clear: both; } .u722ec82276fd1bd606d486b304091d59 { display: block; transition: background-color 250ms; webkit-transition: background-color 250ms; width: 100%; opacity: 1; transition: opacity 250ms; webkit-transition: opacity 250ms; background-color: #95A5A6; } .u722ec82276fd1bd606d486b304091d59:active , .u722ec82276fd1bd606d486b304091d59:hover { opacity: 1; transition: opacity 250ms; webkit-transition: opacity 250ms; background-color: #2C3E50; } .u722ec82276fd1bd606d486b304091d59 .centered-text-area { width: 100%; position: relative ; } .u722ec82276fd1bd606d486b304091d59 .ctaText { border-bottom: 0 solid #fff; color: #2980B9; font-size: 16px; font-weight: bold; margin: 0; padding: 0; text-decoration: underline; } .u722ec82276fd1bd606d486b304091d59 .postTitle { color: #FFFFFF; font-size: 16px; font-weight: 600; margin: 0; padding: 0; width: 100%; } .u722ec82276fd1bd606d486b304091d59 .ctaButton { background-color: #7F8C8D!important; color: #2980B9; border: none; border-radius: 3px; box-shadow: none; font-size: 14px; font-weight: bold; line-height: 26px; moz-border-radius: 3px; text-align: center; text-decoration: none; text-shadow: none; width: 80px; min-height: 80px; background: url(https://artscolumbia.org/wp-content/plugins/intelly-related-posts/assets/images/simple-arrow.png)no-repeat; position: absolute; right: 0; top: 0; } .u722ec82276fd1bd606d486b304091d59:hover .ctaButton { background-color: #34495E!important; } .u722ec82276fd1bd606d486b304091d59 .centered-text { display: table; height: 80px; padding-left : 18px; top: 0; } .u722ec82276fd1bd606d486b304091d59 .u722ec82276fd1bd606d486b304091d59-content { display: table-cell; margin: 0; padding: 0; padding-right: 108px; position: relative; vertical-align: middle; width: 100%; } .u722ec82276fd1bd606d486b304091d59:after { content: ""; display: block; clear: both; } READ: Ancient Greeks and Romans Essay and believes that Jim was taken and sold because it is Gods way of saying that he will not allow people who help slaves to run away go unpunished. God watching over him makes Huck so scared that he decides to pray and try to become a good person. Huck tries to pray to become a good person, but knows that he will and does not want to become one, and he can not pray a lie. So Huck decides to write